Low-Cost Silicon Nitride Ceramics
Recently, however, a new technology has been developed that can significantly lower the cost of manufacturing Si3N4 ceramics. This technology offers manufacturers of silicon nitride and aluminum oxide (Al2O3) ceramics the potential to broaden their market share and explore a variety of applications that were previously unattainable.
The New Si3N4 TechnologyThe new technology was developed over a period of 20 years at Eaton Corp. in Southfield, Mich., for high-volume automotive operations. In 1999, the company granted James Edler, head of the Si3N4 R&D operation, an exclusive worldwide license for the technology. Edler immediately created a new company, SiNeramics Inc. based in Ferndale, Mich., to further develop the technology and explore potential new markets.
According to Edler, there’s nothing notable about the silicon metal material itself—it’s the formulation that makes it successful. “Companies originally made silicon nitride using silicon metal, but they couldn’t get it to sinter properly and they had problems with the nitridation cycle being highly exothermic, which caused problems in their furnaces. For these reasons, the bulk of researchers stopped making silicon nitride from silicon metal and started making it instead from chemically derived silicon nitride powders—a material that was much more expensive but gave them the results they needed,” Edler says. “The problem with that route is that the cost never came down. Silicon nitride powders, and the rest of the processing that goes with them, have always been extremely expensive.”
The new technology is based on water processing and the use of a low-cost cerium oxide additive, which enables manufacture similar to aluminum oxide ceramics. The recipes are provided through a licensing agreement with SiNeramics. Like conventional Si3N4 and Al2O3, the material is balled milled, and the resulting slurry is spray dried into a powder form. The powder is then pressed into a green shape and nitrided and/or sintered at under 1800°C—a lower temperature than what is required for conventional silicon nitrides—with conventional furnace technology and with little or no over-pressure during sintering. The finished blank can then be ground, if necessary, to complete the final product.
“It’s really a simple process,” says Edler.
Market OpportunitiesExtensive testing on components produced with the new technology has shown that the performance of the end product is equal to that of most conventional Si3N4 components and, in many cases, far exceeds that of conventional Al2O3 components (see Table 1), allowing the technology to be used in a range of applications.
The high durability, thermal shock resistance and creep resistance of Si3N4 make it ideally suited for refractory applications in alumina and steel manufacturing plants. For instance, rather than making furnace nozzles and valves from an expensive Si3N4 or a cheap refractory with a short lifespan, the new technology can be used to manufacture a relatively inexpensive Si3N4 that will increase profits for the Si3N4 manufacturer and lower maintenance and replacement costs for the aluminum or metal producer. Tests are also under way to evaluate the use of the Si3N4 technology in refractory bricks and other high-temperature applications. In the past, conventional Si3N4 has been far too expensive for these types of applications.
Silicon nitride is also impervious to aluminum, making it ideal for aluminum casting applications. And because it can be threaded and machined to intricate shapes and sizes, it can also be used for brazing fixture components and other intricate applications.
In short, the technology enables Si3N4 to become a serious consideration for just about any ordinary, average refractory or ceramic application. “Silicon nitride is no longer for the exclusive world of the turbine engine, fighter jet and others who can afford to pay high prices,” says Edler. “With the new Si3N4 technology, it’s now available to the masses.”
For More InformationFor more information about the new Si3N4 technology and licensing opportunities, contact SiNeramics, 1980 E. Nine Mile Rd., Ferndale, MI 48220; (248) 542-6756; fax (248) 542-6784; or e-mail email@example.com. The company also welcomes visits to its Ferndale manufacturing facility.
SIDEBAR: Si3N4 Bearings Lead to Roller Hockey ChampionshipsReal-life tests of Si3N4 ceramic ball bearings in roller hockey skates have made several Michigan roller hockey teams firm believers in the technology. During the Winter Indoor Nationals Championships held by NARCh (North American Roller Hockey Championships), four teams—Tour Venom, Easton Detroit, Detroit Iron Horse and Michigan State University—wore skates with the Si3N4 ceramic ball bearings, and all four teams won the championship in their division.
James Edler had the opportunity to witness the Michigan State game. “I was sitting in between the Michigan State and Altoona fans, and you could hear them going back and forth trying to figure out what had changed,” Edler says. “It was a 9-1 match, with Michigan State beating Altoona, and this was the score by the second period. Michigan State had played the day before with different skates, and it had been a 3-3 tie. It was such a remarkable difference.”
The skates have also led to victories for numerous speed skaters.