A new flexible ceramic is competing with tile and
conventional wallpaper as a hard-wearing, easy-care wall covering.

A continual patented process is used to apply a ceramic
coating to the flexible carrier material, which is then hardened before it is
given an anorganic topcoat.

Long-term sprinkler tests demonstrated that even after a
week of thorough soaking, no water managed to penetrate the material.
The Miller family is very happy. They have a cottage in
the country, a small garden with a sandbox and a swing for the children, and a
freshly tiled terrace-everything looks great. The only project that Peter
Miller, a painter and decorator by trade, has yet to tackle is the bathroom.
Tiling is not exactly something he's crazy about, however. Cutting tile can be
tough going, and the joins only look good if they run precisely parallel to
each other.
Peter found a new solution for his problem at the Home
Textiles trade fair in Frankfurt,
Germany. Made
by Degussa GmbH, a wholly-owned subsidiary of the German industrial group RAG,
and sold under the name ccflex, the flexible ceramic product offers a number of
advantages over traditional wall coverings. Mary Miller was able to choose the
color shade she wanted, and applying the covering was child's play for Peter
(after all, he's a professional). It took him just one day to get the bathroom
gleaming in a beige-green shade with orange marbling. The wall covering not
only looks superb, it also meets all the norms for fittings and fixtures in
damp locations-even the spray from the shower won't damage the special wall
coating. Three-year-old Lisa Miller has already tried it out; she wants to be a
firewoman when she grows up.
Ceramic has always been regarded as a tough, hard and
brittle substance, and is not something that can generally be rolled up or
applied to a wall using a brush or paint roller. Yet that is precisely what
Creavis Technologies & Innovation, the Research and Development unit of
Degussa GmbH, has managed to achieve. The ccflex flexible ceramic product can
compete with tile and conventional wallpaper as a hard-wearing, easy-care wall
covering.

Figure 1. Four layers make up the flexible ceramic
material. The base (1) consists of a nonwoven polymer that lends the necessary
flexibility. The ceramic material (2) is applied directly on top of this from a
metal oxide compound. The material can be pre-colored if required, or a wide
range of different designs can be stamped onto the material (3). A transparent
topcoat layer (4) is then used.
Understanding the Process
ccflex is based on a technology developed and patented by
Degussa. The technology enables a ceramic coating to be applied to a flexible
carrier material, such as a nonwoven polymer, in a continual process, with
additional anorganic covering layers then added (see Figure 1).
Normally, ceramic materials only achieve their strength
and durability at high temperatures. "We have succeeded in greatly
reducing these temperatures, which otherwise would mean high energy
consumption," explains Martin Wille, Ph.D., who is in charge of production
and technology in the ccflex unit. The ceramic can be anchored and hardened
onto the synthetic matrix at temperatures of approximately 250°C, which is up
to 1000°C lower than traditional methods.
The process involves a special kind of adhesion or
bonding between the carrier and coating. Once the surface has been printed to
specifications, a transparent topcoat is applied. The entire process is
patented, as is the special application.
The ceramic material, which consists of a mix of
different metal oxides, can be colored or stained. Alternatively, patterns or
motifs can be applied to the material after thermal treatment. Conventional
printing processes such as Flexodruck can be used to decorate the material in
this fashion.
Finally, a water-resistant topcoat is added to seal the
surface, and a coating is then added to the reverse side of the material for
adhesion purposes. After the product has undergone quality controls, the
partner company assists in cutting it to standard measurements and packaging it
for shipping.
"We are currently manufacturing 25 m rolls in 70 cm
widths. We will also have 100 cm widths available in the near future,"
says Michael Schulze, the Creavis man responsible for the sale and marketing of
ccflex. In the meantime, Creavis has acquired another production line that will
be placed in its own hall. This production line will be able to produce rolls
in widths of up to 150 cm, which should enable the company to tap into new
markets for coating furniture or work surfaces.

The flexible ceramic material (right) was compared with a
conventional woodchip wallpaper in a flame test. The wallpaper burnt to ashes
within 10 seconds of flame contact. By contrast, the ceramic wall covering only
glowed. It didn't break off into burning parts, and the fire did not spread.
Multiple Benefits
Because it is ceramic, ccflex is scratch proof; resistant
to impact, chemicals and fire; and stable under ultraviolet sun rays. Ease of
use is another important benefit. "Our product is easy to handle because
it is sold by the roll," says Schulze. ccflex can be worked more rapidly
and more affordably than tile, which has to be applied piece by piece and then
grouted. And because there are no joins when the material is applied, there are
far fewer hiding places for dirt to gather or mold to form.
The covering is normally applied using a traditional
dispersion adhesive, which is another advantage. When the Millers move or
redecorate, they can simply remove the wall covering-no more tedious dampening
and scraping off wallpaper. The properties of the product can also be
customized to suit particular purposes. For example, ccflex can be adapted to
help significantly reduce the spread of bacteria and prevent mold from forming.
The product's low weight is another plus that opens the
door to a large number of lightweight construction opportunities in trains,
airplanes and ships, where high functionality combined with a luxurious look is
needed. Demand could be particularly high in the premium segment (i.e., cruise
ships or first class sections in trains and airplanes), especially as the
ceramic material should receive a high fire protection rating.
A Flexible Future
Degussa expects to sell more than 1 million m
2
of flexible ceramic by the end of 2007. Potential customers include architects,
specialist plants and major construction companies. The housing construction
company Rhein-Lippe, a part of the RAG Group, has indicated its interest in the
product and would like to renovate its housing stock using ccflex.
Other applications for ccflex could include wall
coverings in living areas, workrooms and sanitary units, and as decorative
elements in buildings. As a response to all these potential uses, ceramic
surfaces are available in a wide range of colors and designs. The Creavis team
is also developing different designs to meet specific requirements and habits
in the U.S., Great Britain and Germany.
The first ccflex samples met with great interest from
users. Soon it might not be just the Miller family that finds their new
"marble bathroom" exciting. Peter, the professional painter and
decorator, has a good idea of how he can convince his customers as well.
"If necessary, I'll just bring them home with me and show them," he
says. "That will definitely work."
For business
information regarding flexible ceramic wall coverings, contact RAG_s Corporate
Press office at (49) 202177-4299. For product-related questions, call (49)
236549-4666, e-mail info@cc-flex.com or visit www.degussa.com.Links